Fe3O4@NH2@Oxalic Acid: A Convenient Catalyst for Synthesis of Pyrrolinone Derivatives
DOI:
https://doi.org/10.29356/jmcs.v68i2.1910Keywords:
ethylenediamine, amino-functionalization, nano-magnetite, pyrrolinones, green chemistryAbstract
Abstract. In this context, an amine-functionalized magnetite nanoparticle was synthesized from FeCl3•6H2O and 1, 2-ethylenediamine at 110 °C in ethylene glycol within 6 hours. Then, the obtained corresponding Fe3O4@NH2 was used for the preparation of Fe3O4@NH2@oxalic acid as organoacid-magnetic nanoparticles under ultrasonic irradiation at 60 °C within 4 hours. Its chemical structure was characterized by FT-IR, XRD, SEM, VSM, and EDAX spectra. The Fe3O4@NH2@oxalic acid nanoparticles were successfully used for the synthesis of pyrrolinones derivatives in excellent yields of the products (90-95 %) within 6-10 hours at room temperature in ethanol.
Resumen. Se sintetizó una nanopartícula de magnetita funcionalizada con aminas a partir de FeCl3•6H2O y 1,2-etilendiamina a 110 °C en etilenglicol durante 6 horas. Posteriormente, el Fe3O4@NH2 que se obtuvo se utilizó para la preparación de nanopartículas magnéticas organoácidas de Fe3O4@NH2@ácido oxálico por irradiación ultrasónica a 60 °C durante 4 horas. Su estructura química se caracterizó por sus espectros de FT-IR, XRD, SEM, VSM, y EDAX. Las nanopartículas de Fe3O4@NH2@ácido oxálico se utilizaron existosamente para sintetizar derivados de pirrolinonas con rendimientos excelentes (90-95%), en 6-10 horas de reacción a temperatura ambiente en etanol.
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