Chicle Gum from sapodilla (Manilkara zapota) as a Renewable Resource for Metathesis Transformations

Authors

  • Sonia Reyes-Gómez Universidad Nacional Autónoma de México
  • Raúl Montiel Universidad Autónoma Metropolitana-Iztapalapa
  • Mikhail A. Tlenkopatchev Universidad Nacional Autónoma de México

DOI:

https://doi.org/10.29356/jmcs.v62i1.581

Keywords:

Manilkara zapota, chicle gum, essential oils, metathesis, ruthenium catalysts, oligoisoprenes

Abstract

In this study, we report on for the first time the self-metathesis of the chicle gum and cross-metathesis of the chicle gum rubber isolated from the gummy latex of sapodilla (Manilkara zapota) with orange oil, β-pinene and, methyl methacrylate using the Ru-alkylidenes Hoveyda-Grubbs and Grubbs second generation catalysts. There were obtained terpene- and ester-terminated oligoisoprenes, with good yields and selectivities. The present results are a promising starting point for the application of this underexploited renewable resource as a new feedstock for metathesis transformations.

Author Biographies

Sonia Reyes-Gómez, Universidad Nacional Autónoma de México

Instituto de Investigaciones en Materiales

Raúl Montiel, Universidad Autónoma Metropolitana-Iztapalapa

Área de Polímeros, Depto. de Física, DCBI

Mikhail A. Tlenkopatchev, Universidad Nacional Autónoma de México

Instituto de Investigaciones en Materiales

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2018-05-25

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