Removal of Color and Chemical Oxygen Demand Using a Coupled Coagulation-Electrocoagulation-Ozone Treatment of Industrial Wastewater that Contains Offset Printing Dyes

Authors

  • Gabriela Roa-Morales Centro Conjunto de Investigación en Química Sustentable UAEM-UNAM
  • Carlos Barrera-Díaz Centro Conjunto de Investigación en Química Sustentable UAEM-UNAM
  • Patricia Balderas-Hernández Centro Conjunto de Investigación en Química Sustentable UAEM-UNAM
  • Francisco Zaldumbide-Ortiz Centro Conjunto de Investigación en Química Sustentable UAEM-UNAM
  • Horacio Reyes Perez Universidad Autónoma del Estado de México
  • Bryan Bilyeu Xavier University of Louisiana

DOI:

https://doi.org/10.29356/jmcs.v58i3.146

Keywords:

Dye, AHC, Coagulation, Electrocoagulation, Ozonation

Abstract

Industrial offset printing processes generate wastewater with highly colored obtaining values of 5x106 Pt-Co units and great values of chemical oxygen demand (COD) 5.3x10-5 mg L-1. Thus, conventional technologies such as biologicals treatment fail in reaching the discharge limits. In this research, a sequential treatment was applied: coagulation with aluminum hydroxychloride (AHC), electrocoagulation with Al anodes and finally ozonation. Optimal conditions are found when adding 20 mg L-1 AHC, followed by electrocoagulation at 4 A for 50 min, and finally alkaline ozonation for 15 min, resulting in an overall color removal of 99.99% color and 99.35% COD.

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Author Biographies

Horacio Reyes Perez, Universidad Autónoma del Estado de México

Facultad de Química

Bryan Bilyeu, Xavier University of Louisiana

Department of Chemistry

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Published

2017-10-12

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