Influence of EDTA on the Electrochemical Removal of Mercury (II) in Soil from San Joaquín, Querétaro, México

Authors

  • I. Robles Centro de Investigación y Desarrollo Tecnológico en Electroquímica, S. C.
  • T. Serrano Centro de Investigación y Desarrollo Tecnológico en Electroquímica, S. C.
  • J. J. Pérez Centro de Investigación y Desarrollo Tecnológico en Electroquímica, S. C.
  • G. Hernández Universidad Nacional Autónoma de México
  • S. Solís Universidad Nacional Autónoma de México
  • R. García Universidad Nacional Autónoma de México
  • T. Pi Universidad Nacional Autónoma de México
  • E. Bustos Centro de Investigación y Desarrollo Tecnológico en Electroquímica, S. C.

DOI:

https://doi.org/10.29356/jmcs.v58i3.141

Keywords:

Electrokinetic treatment, soil, bentonite, mercury, EDTA

Abstract

The removal of mercury from soil and Ca-bentonite was performed using electrochemical treatment adding ethylendiaminetetra acetic acid (EDTA) as a complexing agent to improve the electrochemical removal of Hg (II) in soil from San Joaquín, Querétaro, México. During the electrokinetic treatment in the presence of 0.1 M EDTA, most of Hg (II) migrates toward the anode obtaining the highest removal efficiencies close to 70 % in bentonite after 9 h. Using 0.1M HCl only 65 % efficiency was attained after 13 h in the cathodic side. EDTA formed a negatively charged stable complex that migrates to the cathode by the application of the electrokinetic treatment across Hg – EDTA synthesized complex.

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Author Biographies

G. Hernández, Universidad Nacional Autónoma de México

Centro de Geociencias

S. Solís, Universidad Nacional Autónoma de México

Centro de Geociencias

R. García, Universidad Nacional Autónoma de México

Centro de Ciencias de la Atmósfera

T. Pi, Universidad Nacional Autónoma de México

Instituto de Geología

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Published

2017-10-12

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