Cordination Compound of Dimethyltin(IV) with N,N,N’N’-Tetraethylethylenediamine: Speciation and Theoretical approach

  • Safaa Said Hassan Cairo University
  • Mohamed Mohamed Shoukry Cairo University
  • Abdel Aziz Qasem Jbarah Al-Hussein Bin Talal University
Keywords: Dimethyltin(IV), N,N,N’,N’-tetraethylethylenediamine, stability constants, DFT calculation

Abstract

The formation equilibria of the dimethyltin(IV) complexes with of N,N,N’,N’-tetraethylethylenediamine (Et4en) in solution were investigated. The stoichiometry and stability constants of the complexes formed in solution phase were determined at different temperatures (15 oC – 35 oC) and in solutions of dioxane-water mixtures of different compositions (15% - 62.5%). The accepted model is composed of the 110, 111, 11-1 and 11-2 species. The thermodynamic parameters H and S associated with the protonation of N,N,N`,N`-tetraethylethylendiamine (Et4en) and its complex formation with the dimethyltin(IV) species were determined. The complex formation reaction is exothermic. The equilibrium constant for the displacement of N,N,N’,N’-tetraethylethylenediamine coordinated to dimethyltin(IV) by some selected DNA constituents was calculated. The Keq values clearly indicate the ability of DNA to displace the coordinated Et4en from its dimethyltin(IV) complex. The nucleotides IMP and GMP have the highest values. The DFT/B3LYP method was used for geometric optimization of the ligand and the complex using the Gaussian 09 program. Also the vibrational frequencies of the ligands and complexes were computed for the optimized geometries. The results shows that there is no imaginary frequencies as found in the calculated vibrational frequencies. The binding energies of the dimethyltin(IV) complexes were calculated. All calculated binding energy values are negative.

Author Biographies

Safaa Said Hassan, Cairo University

Department of Chemistry, Faculty of Science, Giza, Egypt

Mohamed Mohamed Shoukry, Cairo University

Department of Chemistry, Faculty of Science, Giza, Egypt

Islamic University,Department of Chemistry, Faculty of Science, Al-Madinah, Saudi Arabia

Abdel Aziz Qasem Jbarah, Al-Hussein Bin Talal University

Chemistry Department, College of Science, Ma'an Jordan

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Published
04-04-2020