New Pyranoanthocyanins Synthesized from Roselle (Hibiscus sabdariffa L.) Anthocyanins

Authors

  • María del Pilar Guzmán-Figueroa Universidad de las Américas Puebla
  • Ana Eugenia Ortega-Regules Universidad de las Américas Puebla
  • Ana Belén Bautista-Ortín Universidad de Murcia
  • Encarna Gómez-Plaza Universidad de Murcia
  • Cecilia Anaya-Berríos Universidad de las Américas Puebla

DOI:

https://doi.org/10.29356/jmcs.v60i1.65

Keywords:

pyranoanthocyanins, roselle, 4-vinylphenol, acetone, pi-notins, methylpyranoanthocyanins

Abstract

Six new pyranoanthocyanins were synthesized through the reaction between dephinidin-3-sambubioside and cyanidin-3-sam-bubioside, extracted from roselle calyxes, with 4-vinylphenol, acetone and 2-butanone. The reaction products were characterized by liquid chromatography coupled to mass spectrometry (HPLC-TOF-MS), ul-traviolet-visible spectroscopy (UV/Vis) and high-performance liquid chromatography. Those new pigments belong to the families of pino-tins and methylpyranoanthocyanins and show a hypsochromic shift, which results in a more orange colour compared to the red hue of the original anthocyanins. Therefore, these compounds could be used to obtain new colorants more stable against certain factors such as pH.

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Author Biographies

María del Pilar Guzmán-Figueroa, Universidad de las Américas Puebla

Departamento de Ingeniería Química, Alimentos y Ambiental

Ana Eugenia Ortega-Regules, Universidad de las Américas Puebla

Departamento de Ciencias de la Salud

Ana Belén Bautista-Ortín, Universidad de Murcia

Departamento de Tecnología de los Alimentos, Nutrición y Bromatología

Facultad de Veterinaria

Campus Universitario de Espinardo, Murcia

Encarna Gómez-Plaza, Universidad de Murcia

Departamento de Tecnología de los Alimentos, Nutrición y Bromatología

Facultad de Veterinaria

Campus Universitario de Espinardo, Murcia

Cecilia Anaya-Berríos, Universidad de las Américas Puebla

Departamento de Ciencias Químico Biológicas

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2017-10-12

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