Correlation of water-chlorohydrocarbon mutual solubilities using a modified non-quadratic mixing rule and the Cubic-Two-State equation of state
DOI:
https://doi.org/10.29356/jmcs.v63i2.770Keywords:
Mutual Solubilities, Chlorinated Hydrocarbons, Liquid-Liquid Equilibrium, Equation of StateAbstract
The Cubic Two-State equation of state was employed to correlate the measured mutual solubilities of water and 23 chlorinated hydrocarbons (CHCs). Following the scheme framework laid out by Medeiros and Brindis-Flores, a nonquadratic Kabadi-Danner type mixing rule is used, where the water-water dispersive parameter is corrected due to the presence of a hydrophobic solute. The model’s three parameters were adjusted to correlate experimental binary liquid-liquid equilibrium data to relatively high accuracy. The observed minimum in CHC solubility in water near ambient conditions is reproduced reliably. Overall deviations from experimental data were 7.8% for CHC solubility in the aqueous phase and 13% for water solubility in the organic phase.
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Schwille, F. The Science of the Total Environment. 1985, 21, 173-185. DOI: https://doi.org/10.1016/0048-9697(81)90150-9
Stockholm Convention on persistent organic pollutants. 2009, Annexes A–C. 33-51.
Oliveira, M. B.; Coutinho, J. A. P.; Queimada, A. J. Fluid Phase Equilib. 2007, 258, 58-66. DOI: https://doi.org/10.1016/j.fluid.2007.05.023
Economou, I. G.; Tsonopoulos, C. Chem. Eng. Sci. 1997, 52, 511-525. DOI: https://doi.org/10.1016/S0009-2509(96)00441-1
Kabadi, V. N.; Danner, R. P. Ind. Eng. Chem. Process Des. Dev. 1985, 24, 537-541. DOI: https://doi.org/10.1021/i200030a004
Michel, S.; Hooper, H. H.; Prausnitz, J. M. Fluid Phase Equilib. 1989, 45, 173-189. DOI: https://doi.org/10.1016/0378-3812(89)80256-0
Nasrifar, K.; Moshfeghian, M. Fluid Phase Equilib. 2002, 193, 261-275. DOI: https://doi.org/10.1016/S0378-3812(01)00743-9
Reshadi, P.; Nasrifar, K.; Moshfeghian, M. Fluid Phase Equilib. 2011, 302, 179-189. DOI: https://doi.org/10.1016/j.fluid.2010.08.007
Medeiros, M. Fluid Phase Equilib. 2014, 368, 5-13. DOI: https://doi.org/10.1016/j.fluid.2014.02.005
Medeiros, M.; Brindis–Flores, C. C. Ind. Eng. Chem. Res. 2017, 56, 2277-2286. DOI: https://doi.org/10.1021/acs.iecr.6b04436
Senol, A. Fluid Phase Equilib. 2006, 243, 51-56. DOI: https://doi.org/10.1016/j.fluid.2006.02.017
Sengupta, S.; Gupta, S.; Dooley, K. M.; Knopf, F. C. The Journal of Supercritical Fluids 1994, 7, 201-209. DOI: https://doi.org/10.1016/0896-8446(94)90027-2
Medeiros, M.; Tellez–Arredondo, P. Ind. Eng. Chem. Res. 2008, 47, 5723-5733. DOI: https://doi.org/10.1021/ie071397j
Huang S. H.; Radosz M. Ind. Eng. Chem. Res. 1990, 29, 2284-2294. DOI: https://doi.org/10.1021/ie00107a014
Kontogeorgis G. M.; Voutsas, E. C.; Yakoumis, I. V.; Tassios, D. P. Ind. Eng. Chem. Res. 1996, 35, 4310-4318. DOI: https://doi.org/10.1021/ie9600203
Holldorff, H.; Knapp, H. Fluid Phase Equilib. 1988, 44, 195-209. DOI: https://doi.org/10.1016/0378-3812(88)80111-0
Niini, A. Suom. Kemistil. A. 1938, 11, 19-20.
Sadovnikova, L. V.; Komarova, V. F.; Aleksandrova, M. V.; Serafimov, L. A. Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol. 1972, 15, 1891-1894.
Huemer, H.; Wortl, K.; Moser, F. Fluid Phase Equilib. 1983, 11, 311-323. DOI: https://doi.org/10.1016/0378-3812(83)85031-6
Naradoslawsky, M.; Huemer, H.; Moser, F. Monatsh. Chem. 1987, 118, 1129-1142. DOI: https://doi.org/10.1007/BF00811286
Ruiz, F.; Gomis, V.; Botella, R. F. Ind. Eng. Chem., 1988, 27, 648-650. DOI: https://doi.org/10.1021/ie00076a020
Liu, D.; Li, Q.; Chen, Z. Tianranqi Huagong 1994, 19, 52-58.
Malagoni, R. A.; Franco Jr., M. R. Fluid Phase Equilib. 2007, 255, 93-97. DOI: https://doi.org/10.1016/j.fluid.2007.03.032
Van Arkel, A. E.; Vles, S. E. Recl. Trav. Chim. Pays-Bas 1936, 55, 407-411. DOI: https://doi.org/10.1002/recl.19360550507
Staverman, A. J. Recl. Trav. Chim. Pays-Bas 1941, 60, 836-841. DOI: https://doi.org/10.1002/recl.19410601105
McGovern, E. W. Ind. Eng. Chem. 1943, 35, 1230-1239. DOI: https://doi.org/10.1021/ie50408a003
Stephenson, R. M. J. Chem. Eng. Data. 1992, 37, 80-95. DOI: https://doi.org/10.1021/je00005a024
Krupatkin, I. L.; Glagoleva, M. F. Zh. Prikl. Khim. 1969, 42, 1526-1531.
Pearson, C. R.; McConnell, G. Proc. R. Soc. Lond. B. 1975, 189, 305-332. DOI: https://doi.org/10.1098/rspb.1975.0059
Coca, J.; Diaz, R. M.; Pazos, C. Fluid Phase Equilib. 1980, 4, 125-136. DOI: https://doi.org/10.1016/0378-3812(80)80010-0
Gibby, C. W.; Hall, J. J. Chem. Soc. 1931, 691-693 DOI: https://doi.org/10.1039/JR9310000691
Gross, P. M.; Saylor, J. H. J. Am. Chem. Soc. 1931, 53, 1744-1751. DOI: https://doi.org/10.1021/ja01356a016
Matin, N. B.; Zilberman, E. N.; Trachenko, V. I.; Afanasev, V. A. Zh. Prikl. Khim. 1980, 53, 1880-1882.
Bevia, F. R.; Rico, D. P. Fluid Phase Equilib. 1983, 10, 77-93. DOI: https://doi.org/10.1016/0378-3812(83)80006-5
Lo, J. M.; Tseng, C.-L.; Yang, J. Y. Anal. Chem. 1986, 58, 1596-1597. DOI: https://doi.org/10.1021/ac00298a081
Clifford, C. W. J. Ind. Eng. Chem., 1921, 13, 631-632. DOI: https://doi.org/10.1021/ie50139a019
Gross, P. M. J. Am. Chem. Soc. 1929, 51, 2362-2366. DOI: https://doi.org/10.1021/ja01383a008
Donahue, D. J.; Bartell, F. E. J. Phys. Chem., 1952, 56, 480-484. DOI: https://doi.org/10.1021/j150496a016
Abramov, A. A. Zh. Fiz. Khim., 1995, 69, 1722-1723.
Horvath, A. L.; Getzen, F. W.; Maczynska, Z. J. Phys. Chem. Ref. Data. 1999, 28, 395-627. DOI: https://doi.org/10.1063/1.556039
Horvath, A. L.; Getzen, F. W. J. Phys. Chem. Ref. Data. 1999, 28, 649-777. DOI: https://doi.org/10.1063/1.556051
M?czyn?ski, A.; Wisniewska–Goc?owska, B.; Goral, M. J. Phys. Chem. Ref. Data. 2004, 33, 549-577.
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