Methylene: The Linker of Two Aromatic Iminium Salts

Authors

  • Anurag Noonikara-Poyil University of Texas at Arlington
  • Enrique Barragan University of Texas at Arlington
  • Siddappa Patil Jain University
  • Alejandro Bugarin University of Texas at Arlington

DOI:

https://doi.org/10.29356/jmcs.v63i3.525

Keywords:

Aromatic iminium salts, Pi-conjugated triazene, X-ray structure, iodomethane, methylene chloride.

Abstract

A straightforward synthesis of aromatic iminium salts has been developed by coupling 2-Azido-1,3,5-trimethyl benzene with 1,3-ditert-butylimidazolium tetrafluoroborate in basic conditions, followed by treatment with dichloromethane or iodomethane. Herein, we report the synthetic procedure and full characterization data, including X-ray structure analysis, of the expected bis(triazenyl)methane adduct 5. Moreover, we have discovered what constitutes a double carbon-chlorine bond activation.

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Author Biography

Alejandro Bugarin, University of Texas at Arlington

Assistant Professor

Department of Chemistry and Biochemistry

References

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Published

2019-10-17

Issue

Vol. 63 No. 3 (2019): Special Issue: Mexican Chemist Overseas

Section

Regular Articles

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