Evaluation of QuEChERS Method for GC Analysis of Pesticides in Tropical Fruits from Yucatan, Mexico
DOI:
https://doi.org/10.29356/jmcs.v61i4.459Keywords:
Gas chromatography, QuEChERS, multiresidue analysis, pesticides, tropical fruitsAbstract
The pesticides intake causes health problems; therefore, food must not exceed the maximum allowable limits. The aim of this work was the evaluation of a multi-residue method for the determination of eleven pesticides in tropical fruits of Yucatan, Mexico. Pesticide extraction was carried out with acetonitrile and clean-up by dispersive solid phase extraction (QuEChERS method). The extracts were analyzed by GC/MS. The quantification was performed by the external standard matrix match calibration. Most of the quantification limits were below 10 ng×g-1. In 70% of the cases, the relative standard deviation was lower than 15%. The pesticide recoveries ranged from 67.74% to 138.57%. The method allowed the quantification of pesticides in papaya, melon, dragon fruit and sugar apple.Downloads
References
Díez, C., Traag, W. A., Zommer, P., Marinero, P., Atienza, J. J. Chromatogr. A. 2006, 1131, 11-23. DOI: https://doi.org/10.1016/j.chroma.2006.07.046
Ortelli, D., Edder, P., Corvi, C. Anal. Chim. Acta. 2004, 520, 33-45. DOI: https://doi.org/10.1016/j.aca.2004.03.037
Mol, H.G.J., Rooseboom, A., van Dam, R., Roding, M., Arondeus, K., Sunarto, S. Anal Bioanal Chem. 2007, 389, 1715-1754. DOI: https://doi.org/10.1007/s00216-007-1357-1
Arrebola, F.J., Martinez-Vidal, J. L., Mateu-Sanches, M., Álvarez-Castellón F. J. Anal. Chim. Acta 2003, 484, 167-180. DOI: https://doi.org/10.1016/S0003-2670(03)00332-5
Anastassiades, M., Lehotay, S. J. AOAC Int. 2003, 86, 412-43. DOI: https://doi.org/10.1093/jaoac/86.2.412
Gonzales-Curbelo, M. A., Socas-Rodríguez, B., Herrera-Herrera, A. V., Gonzales-Sálamo, J., Hernández-Borges, J. & Rodríguez-Delgado, M. A. Trends Anal. Chem. 2015, 71, 169-185. DOI: https://doi.org/10.1016/j.trac.2015.04.012
Lehotay, S., Maótovská, K. J. AOAC Int. 2005, 88, 630-638. DOI: https://doi.org/10.1093/jaoac/88.2.630
Lehotay, S.J., Son, K. A., Kwon, H., Koesukwiwat, U. Fu, W., Mastovska, K., Hoh, E., Leepipatpiboon, N. J. Chromatogr. A. 2010, 1217, 2548-2560. DOI: https://doi.org/10.1016/j.chroma.2010.01.044
Wilkowska, A., Biziuk, M. Food Chem. 2011, 125, 803-812. DOI: https://doi.org/10.1016/j.foodchem.2010.09.094
Cie?lik, E., Sadowska-Rociek, A., Molina-Ruis, J.M., Surma-Zadora, M. Food Chem. 2011, 125, 773-178. DOI: https://doi.org/10.1016/j.foodchem.2010.09.019
Amelin, V.G., Lavrukhin D.K., Tretýakov, A.U. J. Anal. Chem. 2013, 68, 912-923. DOI: https://doi.org/10.1134/S1061934813080029
Bakirci, G. T., Yaman-Acay, D. B., Bakirci, F., Otles, S. Food Chem. 2014, 160, 379-392. DOI: https://doi.org/10.1016/j.foodchem.2014.02.051
Rajski, L., Gómez-Ramos M. M., Fernández-Alba, A. R. J. Chromatogr. A. 2014, 1360, 119-127. DOI: https://doi.org/10.1016/j.chroma.2014.07.061
Wang, J., Chow, W., Chang, J., Wong j. W. J. Agricultural Food Chem. 2014, 62, 10375-10391. DOI: https://doi.org/10.1021/jf503778c
Alvarado, J., González, R. L., Cobos, V. M. Ciencia y desarrollo 1997, 23, 51-57.
Moguel-Mena, J.A. Infocampo-Gaceta rural de Yucatán 2009, 3, 15.
Cobos, V. M., Mora, M. A. Revista de Toxicología 2006, 23, 17-23. DOI: https://doi.org/10.3917/lpm.017.0023
Liu, M., Hashi, Y., Song, Y., Lin, J. M. J. Chromatogr. A. 2005, 1097, 183-187. DOI: https://doi.org/10.1016/j.chroma.2005.10.022
Mezcua, M., Martnez-Uros, A, M.,Wylie P.L., Fernández-Alba, A.R. J. AOAC Int. 2009, 92, 1790-1806. DOI: https://doi.org/10.1093/jaoac/92.6.1790
Diniz-Madureira, F., da Silva-Oliveira, F.A., Robert de Souza, W., Pontelo, A. P., Goncalves de Oliveira, M. L., Silva, G. Food Addit. Contam. 2012, 29, 665-678. DOI: https://doi.org/10.1080/19440049.2011.623837
Da Silva-Sousa, J., Carius, de Castrom, R., Albuquerque-Andrade, A., Gomes-Lima, C., Lima, L. K., Liberato-Milhome, M.A., Ferreira do Nascimento, R. Food Chem. 2013, 141, 2675-2681. DOI: https://doi.org/10.1016/j.foodchem.2013.05.027
Payá, P., Anastassiades, M., Mack, D., Sigalova, I., Tasdelen, B., Oliva, J., Barba, A. Anal Bioanal Chem. 2007, 389, 1697-1714. DOI: https://doi.org/10.1007/s00216-007-1610-7
Cherta, L., Beltran, J., López, F., Hernández, F. Food Anal. Met. 2013, 6, 1170-1187. DOI: https://doi.org/10.1007/s12161-012-9524-1
Kromidas, S. HPLC made to measure: a practical handbook for optimization. Wiley- VCH, 2006. DOI: https://doi.org/10.1002/9783527611973
Association of Official Analytical Chemist. Official Method of Analysis of the Association of Official Analytical Chemists. Horwitz, W., & Latimer, G. W. (Eds). (18th ed). (ch 10, pp 17–26).
Gaithersburg, MD, USA: AOAC International. 2007.
Costa, F.P., Souza-Caldas, S., Prime, E.G. Food Chem. 2014, 165, 587-593. DOI: https://doi.org/10.1016/j.foodchem.2014.05.099
Hajšlová, J., Zrostlíková, J. J. Chromatogr. A. 2003, 1000, 181-197. DOI: https://doi.org/10.1016/S0021-9673(03)00539-9
Poole, C.F. J. Chromatogr. A. 2007, 1158, 241-250. DOI: https://doi.org/10.1016/j.chroma.2007.01.018
Aparecida de Sousa, F., Guido-Costa, A.I., Lopez –Ribeiro de Queiroz M.E., Teófilo R.F., Agusto-Neves A., Paqulino de Pinho, G. Food Chem. 2012, 135, 179-195. DOI: https://doi.org/10.1016/j.foodchem.2012.04.063
Lacassie, E., Dreyfuss, M.F., Daguet, J.L., Vignaud, M., Marquet, P., Lach?tre, G. J. Chromatogr. A. 1998, 805, 319-326. DOI: https://doi.org/10.1016/S0021-9673(97)01305-8
Pesticide, EU- MRLs. Consulted on 23 December 2014. URL. http://ec.europa.eu/sanco_pesticides/public/?event=homepage&language=EN
United States Department of Agriculture. Agricultural Marketing Service (2011). URL http://www.ams.usda.gov/AMSv1.0/farmersmarkets
Commission Regulation (EC) 396/2005 of the European Parliament and of the Council of 23 February 2005 on maximum residue levels of pesticides in or on food and feed of plant and animal origin and amending Council Directive 91/414/EEC. 2005R0396-EN-10.04.2008-002.001,246.
Hjorth, K., Johansen, K., Holen, B., Andersson, A., Christensen, H.B., Siivinen, K., & Toome, M.. Food Control. 2011, 22, 1701-1706. DOI: https://doi.org/10.1016/j.foodcont.2010.05.017
Camino-Sánchez, F. J., Zafra-Gómez, A., Ruiz-Garcá, J., Bermúdez-Peinado, R., Ballesteros, O., Navalon, A., Vílchez J. L. J. Food Compos. Anal. 2011, 24, 427-440. DOI: https://doi.org/10.1016/j.jfca.2010.11.009
Downloads
Published
Issue
Section
License
Authors who publish with this journal agree to the following terms:
- Authors retain copyright and grant the journal right of first publication with the work simultaneously licensed under a Creative Commons Attribution License that allows others to share the work with an acknowledgement of the work's authorship and initial publication in this journal.
- Authors are able to enter into separate, additional contractual arrangements for the non-exclusive distribution of the journal's published version of the work (e.g., post it to an institutional repository or publish it in a book), with an acknowledgement of its initial publication in this journal.
