A Review of Mexican Contributions to Li₂CuO₂ and its Chemical Modifications as Cathode Materials for Lithium-Ion Batteries
DOI:
https://doi.org/10.29356/jmcs.v68i4.2294Keywords:
Li2CuO2, cation doping, anion doping, dual doping, in situ analysisAbstract
Over the past few decades, battery research has primarily focused on reducing costs and increasing energy density. There have been significant efforts to identify alternative cathode materials that could replace cobalt-based ones, with the goal of finding more environmentally friendly and cost-effective options. In this context, copper-based cathodes have emerged as promising candidates. The appeal of copper-based cathodes lies in their relatively high abundance, particularly in Mexico, their high theoretical energy density, and the potential to enhance their properties by altering their chemical structure. In recent years, numerous research initiatives in Mexico have aimed to make Li2CuO2 cathodes a viable option. This review examines the recent advances and future perspectives of these efforts, with a particular emphasis on the latest attempts to modify the synthesis route and incorporate multiple dopants to create synergistic effects.
Resumen. Durante las últimas décadas, la investigación sobre baterías se ha enfocado principalmente en la disminución de costos y el incremento de la densidad energética. Se han realizado importantes esfuerzos para identificar materiales catódicos alternativos que podrían reemplazar a los materiales basados en cobalto, con el objetivo de encontrar opciones rentables y con menor impacto al medio ambiente. En este contexto, los materiales catódicos basados en cobre se han convertido en candidatos prometedores. El interés por los cátodos basados en cobre radica en su abundancia relativamente alta, particularmente en México, su alta densidad energética teórica y la cualidad de mejorar sus propiedades alterando su estructura química. En los últimos años, numerosas propuestas de investigación en México han tenido como objetivo hacer de los cátodos de Li2CuO2 una opción viable. Este resumen recopila los avances recientes y las perspectivas a futuro de estos esfuerzos, con especial énfasis en los últimos intentos de modificar la ruta de síntesis y, a su vez, incorporar múltiples dopantes para crear efectos sinérgicos.
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